Spray a bundt pan with non-stick cooking spray.
Place frozen rolls in pan.
Sprinkle the butterscotch pudding and the orange zest over the frozen rolls.
In a medium bowl, add melted butter, brown sugar, and orange extract. Stir to combine.
Pour butter mixture over rolls.
Cover pan with greased foil and place in a warm place overnight.
In the morning, bake at 350°F for 25 minutes.
Immediately invert rolls onto a large plate. Serve and enjoy!