Preheat oven to 350°F. Grease and flour two 8-inch round cake pans and line the bottoms with parchment paper.
In a large bowl, sift together flour, cocoa powder, granulated sugar, baking powder, baking soda, and kosher salt. Whisk to combine evenly.
In a separate medium bowl, whisk together hot brewed coffee, buttermilk, vegetable oil, eggs, and vanilla until smooth and well blended.
Pour the wet ingredients into the dry ingredients. Mix gently until the batter is completely smooth. The batter will be thin, and that’s okay.
Divide the batter evenly between the prepared pans. Bake for 30 to 35 minutes, or until a toothpick inserted into the center comes out with moist crumbs, but no wet batter.
Let the cakes cool in the pans for 10 minutes, then turn them out onto wire racks. Remove parchment and let cool completely before frosting.